Surface complexation effects on phosphate adsorption to ferric iron oxyhydroxides along pH and salinity gradients in estuaries and coastal aquifers   总被引：3，自引：0，他引：3  

Claudette Spiteri  Philippe Van Cappellen  Pierre Regnier 《Geochimica et cosmochimica acta》2008,72(14):3431-3445

Non-conservative behavior of dissolved inorganic phosphate (DIP) in estuaries is generally ascribed to desorption from iron and aluminum (hydr)oxides with increasing salinity. Here, we assess this hypothesis by simulating the reversible adsorption of phosphate onto a model oxide (goethite) along physico-chemical gradients representative of surface and subsurface estuaries. The simulations are carried out using a surface complexation model (SCM), which represents the main aqueous speciation and adsorption reactions of DIP, plus the ionic strength-dependent coulombic interactions in solution and at the mineral-solution interface. According to the model calculations, variations in pH and salinity alone are unlikely to explain the often reported production of DIP in surface estuaries. In particular, increased aqueous complexation of phosphate by Mg²⁺ and Ca²⁺ ions with increasing salinity is offset by the formation of ternary Mg-phosphate surface complexes and the drop in electrical potential at the mineral-water interface. However, when taking into account the downstream decrease in the abundance of sorption sites, the model correctly simulates the observed release of DIP in the Scheldt estuary. The sharp increase in pH accompanying the admixing of seawater to fresh groundwater should also cause desorption of phosphate from iron oxyhydroxides during seawater intrusion in coastal aquifers. As for surface estuaries, the model calculations indicate that significant DIP release additionally requires a reduction in the phosphate sorption site density. In anoxic aquifers, this can result from the supply of seawater sulfate and the subsequent reductive dissolution of iron oxyhydroxides coupled to microbial sulfate reduction.  相似文献   

Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates     

Philippe E. Raison  Regis Jardin  Daniel Bouëxière  Rudy J. M. Konings  Thorsten Geisler  Claudiu C. Pavel  Jean Rebizant  Karin Popa 《Physics and Chemistry of Minerals》2008,35(10):603-609

The crystallographic structures of the synthetic cheralite, CaTh(PO₄)₂, and its homolog CaNp(PO₄)₂ have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO₄ (Ln = La to Gd). The space group is P2₁/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO₄)₂ are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R _wp = 4.87%, R _p = 3.69% and R _B = 3.99%. For CaNp(PO₄)₂, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R _wp = 6.74%, R _p = 5.23%, and R _B = 6.05%. The results indicate significant distortions of bond length and angles of the PO₄ tetrahedra in CaTh(PO₄)₂ and to a lesser extent in CaNp(PO₄)₂. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO₄)₂. A comparison with the isostructural compounds LnPO₄ (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca²⁺ and Th⁴⁺ introduces a distortion of the PO₄ tetrahedra.  相似文献   

Evolution of the Axial Geometry of the Southwest Indian Ocean Ridge between the Melville Fracture Zone and the Indian Ocean Triple Junction – Implications for Segmentation on Very Slow-Spreading Ridges     

Parson  Lindsay  Sauter  Daniel  Mendel  Véronique  Patriat  Philippe  Searle  Roger 《Marine Geophysical Researches》1997,19(6):535-552

Geophysical data from 900 km of the Southwest Indian Ridge are used todescribe the pattern of evolution of the plate boundary between 61° Eand 70° E over the past 20 million years. The SWIR is anobliquely-opening, ultra slow-spreading axis, and east of61° E comprises a series of ridge sections, each about 100–120 kmin length. The orientation of these sections varies fromsub-orthogonal to oblique to the approximately N–S spreadingdirection. In general, the suborthogonal sections are shallower, commonlysubdivided into an array of discrete axial segments, and carry recognisablecentral magnetic anomalies. The majority of the oblique sections are single,continuous rifts without continuous axial magnetic signatures.Morphotectonics of the Southwest Indian Ridge crust have not previously beenwell constrained off-axis, and we here present sidescan sonar andswath bathymetric data up to 100 km from the ridge to demonstrate the complexities of its spatial and temporal evolution.A model is proposed that the segmentation style correlates with analong-axis variation between: (a) relatively thick crustal sections which overlie mantle sections with higher magmatic supply created in orthogonally-spreading segments and (b) those oblique sections associated with cooler, magmatically-starved mantle and thinner crust. These latter sections are formed at broad offset zones in theplate boundary, more precisely defined on faster-spreading ridges asnontransform discontinuities. The nonsystematic pattern of crustalconstruction, extensional basin formation and the absence of extension-parallel traces of discontinuities off-axis suggest that the oblique spreading sections are not fixed in space or time.  相似文献   

Viability theory for an ecosystem approach to fisheries   总被引：1，自引：1，他引：1  

Cury  Philippe M.; Mullon  Christian; Garcia  Serge M.; Shannon  Lynne J. 《ICES Journal of Marine Science》2005,62(3):577-584

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Active spreading and hydrothermalism in North Fiji Basin (SW Pacific). Results of Japanese French Cruise Kaiyo 87     

Jean-Marie Auzende  Eiichi Honza  Xavier Boespflug  Satendra Deo  Jean-Philippe Eissen  Jun Hashimoto  Philippe Huchon  Junichiro Ishibashi  Yo Iwabuchi  Philip Jarvis  Masato Joshima  Kiyoyuki Kisimoto  Yasuto Kuwahara  Yves Lafoy  Tsuyoshi Matsumoto  Jean-Pierre Maze  Kiyohiko Mitsuzawa  Hiroyasu Monma  Takeshi Naganuma  Yukihiro Nojiri  Suguru Ohta  Kiyoshi Otsuka  Yoshihisa Okuda  Hélène Ondreas  Akira Otsuki  Etienne Ruellan  Myriam Sibuet  Manabu Tanahashi  Takeo Tanaka  Tetsuro Urabe 《Marine Geophysical Researches》1990,12(4):269-283

The aim of the Japanese-French Kaiyo 87 cruise was the study of the spreading axis in the North Fiji Basin (SW Pacific). A Seabeam and geophysical survey allowed us to define the detailed structure of the active NS spreading axis between 16° and 22° S and its relationships with the left lateral motion of the North Fiji Fracture Zone. Between 21° S and 18°10′ S, the spreading axis trends NS. From 18°10 S to 16°40 S the orientation of the spreading axis changes from NS to 015°. North of 16°40′ S the spreading axis trends 160°. These two 015° and 160° branches converge with the left lateral North Fiji fracture zone around 16°40′ S to define an RRFZ triple junction. Water sampling, dredging and photo TV deep towing give new information concerning the hydrothermal activity along the spreading axis. The discovery of hydrothermal deposits associated with living communities confirms this activity.  相似文献   

Distribution and transfer of trace elements in the Western Mediterranean     

Gerard Copin-Montegut  Philippe Courau  Emmanuel Nicolas 《Marine Chemistry》1986,18(2-4)

Results concerning the concentration of cadmium and lead in Mediterranean waters collected during the 2nd PHYCEMED cruise (Oct. 1983) are discussed. Sampling has been performed at seven stations in the Western Mediterranean Basin, two in the Strait of Gibraltar and the near Atlantic, two in the Sicily Strait and the Eastern Basin.In the Western Basin the observations are in fair agreement with those of PHYCEMED 1. Cadmium has a fairly homogeneous distribution vertically as well as from one station to another, with an average concentration of 8 ng l⁻¹; while lead shows a slight but continuous decrease in concentrations with depth (from at least 50 ng l⁻¹ in surface waters to 20 or 25 ng l⁻¹ at depth). On the other hand, at the basin boundaries, where waters from different origins are present, vertical distributions appear very different. On the basis of calculated water budgets it can be estimated that the Mediterranean Sea discharges about 200 t y⁻¹ of cadmium and about 250 t y⁻¹ of lead into the Atlantic Ocean while 1000 t y⁻¹ of lead are transferred from the Western to the Eastern Basin.  相似文献   

La Distribution Du Nitrite Dans Le Systeme Des Courants Equatoriaux De L'OCean Pacifique, A 170{degrees}E     

Hisard  Philippe; Piton  Bernard 《ICES Journal of Marine Science》1969,32(3):303-317

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Nonparametric Estimates of the Sea State Bias for the Jason-1 Radar Altimeter   总被引：3，自引：0，他引：3  

Sylvie Labroue  Philippe Gaspar  Joel Dorandeu  Oz Zanif    F. Mertz  Patrick Vincent  Denis Choquet 《Marine Geodesy》2004,27(3):453-481

The Jason-1 sea state bias (SSB) is analyzed in depth from the first year of GDR products. Compared to previous missions, this work benefits from two aspects of the empirical determination of the SSB from the altimetric data themselves. First, from a methodological point of view, a nonparametric technique (NP) has been developed and largely tested on TOPEX/Poseidon 1, GFO and Envisat data. The NP estimator has proven to be a useful tool in the SSB estimation, and it is now mature enough to be used for a refined analysis. On the other hand, the SSB can be extracted from three different data sets (crossovers, collinear data, and residuals) with different characteristics. It is then possible to cross calibrate various estimations of the SSB models and to determine the most accurate one. A systematic comparison is made between these different estimates for the Jason-1 altimeter. The collinear and crossover data sets yield very similar estimates despite their difference of spatial and temporal distributions. These SSB models assure consistency with the TOPEX mission when comparing Jason-1 and TOPEX residuals during the tandem phase. Thanks to the present work, the impact of the short wavelengths filtering on the SSB estimation is evidenced. More generally, our understanding of potential errors affecting the sea surface height and their impact onto the SSB estimation is also improved.  相似文献   

Étude des grands bancs de sable du Sud-est de la mer Celtique     

Philippe Bouysse  Robert Horn  Francis Lapierre  François Le Lann 《Marine Geology》1976,20(3):251-275

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Propagation of the Southwest Indian Ridge at the Rodrigues Triple Junction     

Sauter  Daniel  Mendel  Véronique  Rommevaux-Jestin  Céline  Patriat  Philippe  Munschy  Marc 《Marine Geophysical Researches》1997,19(6):553-567

The analysis of multibeam bathymetric data of the Southwest Indian Ridge(SWIR) domain between the triple junction traces from 68° E to theRodrigues Triple Junction (RTJ; 70° E) reveals the evolution of thisridge since magnetic anomaly 4 (8 Ma). Image processing has been used toshow that the horizontal component of strain due to a network of normal stepfaults increases dramatically between 69°30 E and the RTJ. Thisarea close to the RTJ is characterized by a deep graben at the foot of thetriple junction trace on the African plate and by a narrow fault-boundedridge that joins an offset of the trace on the Antarctic plate. In thatarea, spreading is primarily amagmatic and dominated by tectonic extensionprocesses. To the west of 69°30 E, some lobate bathymetricfeatures atop of a large topographic high suggest volcanic constructions.Between 68°10 E and 69°25 E the southern flank of theSWIR domain is wider than the northern one and is characterized by a series of 7 en echelon bathymetric highs similar in size,shape and orientation to the one centred at 69°30E near the present-day triple junction. Their en echelon organization along the triple junction trace on the Antarctic plate and the typical lack of conjugated parts on the northern flank show that these bathymetric highs have been shifted to the south by successive northward relocalisations of the SWIR rifting zone. This evolution results in the asymmetric spreading of the SWIR in the survey area. The off-axis bathymetric highs connect to the offsets of the triple junction trace on the Antarctic plate when the Southeast Indian Ridges lightly lengthenstoward the northwest and the triple junction is relocated to the north. We propose that the SWIR lengthens toward the northeast with two propagation modes: 1) a continuous and progressive propagation with distributed deformation in preexisting crust of the Central Indian Ridge, 2) a discontinuous propagation with focusing of the deformation in a rift zone when the triple junction migrates rapidly to the north. The modes of propagation of the SWIR are related to different localisation and distribution of strain which are in turn controlled by changes of the triple junction configurations due to propagation, recession or a symmetric spreading on the Central and Southeast Indian Ridges.  相似文献